| Titre : | Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics | | Type de document : | texte imprimé | | Auteurs : | Malcom D.E. Forbes, Editeur scientifique | | Editeur : | New York : Wiley | | Année de publication : | 2010 | | Importance : | XXII, 370 p. | | Présentation : | ill. | | Format : | 24 cm | | ISBN/ISSN/EAN : | 978-0-470-39009-2 | | Note générale : | Bibliogr. p.353-357.- Index | | Langues : | Anglais (eng) | | Mots-clés : | Radicaux libres (chimie)
Réactivité (chimie)
Cations
Charbon actif
Free radicals (Chemistry)
Carbon, Activated
Reactivity (Chemistry) | | Index. décimale : | 54.024 Radicaux | | Résumé : | With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates.
Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers:
* A discussion of the relevant theory
* Mechanistic chemistry, with an emphasis on synthetic utility
* Molecular structure and mechanism, focusing on computational methods
* Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects
* Free radical chemistry in macromolecules
Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states.
This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products. | | Note de contenu : | Au sommaire:
1. A Brief History of Carbon Radicals
2. Intermolecular Radical Additions to Alkynes: Cascade-Type
3. Radical Cyclizations
4. Radical Cation Fragmentation Reactions in Organic Synthesis
5. Selectivity in Radical Cation Cycloadditions
6. The Stability of Carbon-Centered Radicals
7. Interplay of Stereoelectronic Vibrational and Environmental Effects in Tuning Physicochemical Properties of Carbon-Centered Radicals
8. Unusual Structures of Radical Ions in Carbon Skeletons: Nonstandard Chemical Bonding by Restricting Geometries
9. Magnetic Field Effects on Radical Pairs in Homogeneous Solution
10. Chemical Transformations Within the Paramagnetic World Investigated by Photo-CIDNP
11. Spin Relaxation in Ru-Chromophore-Linked Azine/Diquat Radical Pairs |
Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics [texte imprimé] / Malcom D.E. Forbes, Editeur scientifique . - New York : Wiley, 2010 . - XXII, 370 p. : ill. ; 24 cm. ISBN : 978-0-470-39009-2 Bibliogr. p.353-357.- Index Langues : Anglais ( eng) | Mots-clés : | Radicaux libres (chimie)
Réactivité (chimie)
Cations
Charbon actif
Free radicals (Chemistry)
Carbon, Activated
Reactivity (Chemistry) | | Index. décimale : | 54.024 Radicaux | | Résumé : | With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates.
Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers:
* A discussion of the relevant theory
* Mechanistic chemistry, with an emphasis on synthetic utility
* Molecular structure and mechanism, focusing on computational methods
* Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects
* Free radical chemistry in macromolecules
Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states.
This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products. | | Note de contenu : | Au sommaire:
1. A Brief History of Carbon Radicals
2. Intermolecular Radical Additions to Alkynes: Cascade-Type
3. Radical Cyclizations
4. Radical Cation Fragmentation Reactions in Organic Synthesis
5. Selectivity in Radical Cation Cycloadditions
6. The Stability of Carbon-Centered Radicals
7. Interplay of Stereoelectronic Vibrational and Environmental Effects in Tuning Physicochemical Properties of Carbon-Centered Radicals
8. Unusual Structures of Radical Ions in Carbon Skeletons: Nonstandard Chemical Bonding by Restricting Geometries
9. Magnetic Field Effects on Radical Pairs in Homogeneous Solution
10. Chemical Transformations Within the Paramagnetic World Investigated by Photo-CIDNP
11. Spin Relaxation in Ru-Chromophore-Linked Azine/Diquat Radical Pairs |
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54.022 Radicaux
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