| Titre : | Cumulenes in click reactions | | Type de document : | texte imprimé | | Auteurs : | Ulrich, Henri, Auteur | | Editeur : | New York : Wiley | | Année de publication : | 2009 | | Importance : | 552 p. | | Présentation : | ill. | | Format : | 25 cm | | ISBN/ISSN/EAN : | 978-0-470-77932-3 | | Note générale : | Notes bibliogr. - Index | | Langues : | Anglais (eng) | | Mots-clés : | Cumulènes
Réactions chimiques
Alcènes
Alkenes
Chemical reactions | | Index. décimale : | 66.091 Principaux types de transformations chimiques.Synthèses.Réaction des composants organiques et inorganiques en général | | Résumé : | Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". This book presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of introduction to the chemistry of cumulenes, one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts, two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes and diarsaallenes, 1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes, 1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides, 1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes, noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation. Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry. | | Note de contenu : | In summary :
1. General Introduction.
2. Carbon Cumulenes.
3. Dicarbon Cumulenes.
4. Tricarbon Cumulenes.
5. Noncarbon Cumulenes. |
Cumulenes in click reactions [texte imprimé] / Ulrich, Henri, Auteur . - New York : Wiley, 2009 . - 552 p. : ill. ; 25 cm. ISBN : 978-0-470-77932-3 Notes bibliogr. - Index Langues : Anglais ( eng) | Mots-clés : | Cumulènes
Réactions chimiques
Alcènes
Alkenes
Chemical reactions | | Index. décimale : | 66.091 Principaux types de transformations chimiques.Synthèses.Réaction des composants organiques et inorganiques en général | | Résumé : | Cumulenes are organic molecules with two or more cumulative (consecutive) double bonds. Their reactions often proceed at room temperature, with or without a catalyst, and are stereospecific, giving the reaction products in high yields - features characteristic of "click reactions". This book presents a comprehensive list of cumulene systems and their reactions, with an emphasis on their "click-like" nature. The chapters are structured according to the number of carbon atoms in the system, including coverage of introduction to the chemistry of cumulenes, one-carbon cumulenes: sulfines, sulfenes, thiocarbonyl S-imides, thiocarbonyl S-sulfides, and 1-aza-2-azoniaallene salts, two-carbon cumulenes: carbon oxides, carbon sulfides, carbon nitrides (isocyanates, isothiocyanates, and carbodiimides), phosphaallenes and diarsaallenes, 1,2-dicarbon cumulenes: ketenes, thioketenes, ketenimines, 1-silaallenes, 1-phosphaallenes, and other metal allenes, 1,3-dicarbon cumulenes: thiocarbonyl S-ylides, 2-azaallenium salts, 1-oxa-3-azoniabutatriene salts, 1-thia-3-azoniabutatriene salts, and phosphorous ylides, 1,2,3-tricarbon cumulenes: allenes, butatrienes, higher cumulenes and heterobutatrienes, noncarbon cumulenes: azides, triazaallenium salts, sulfur oxides, sulfur nitrides, N-sulfinylamines, sulfurdiimides, and dithionitronium cation. Cumulenes in Click Reactionsis an essential guide for researchers and advanced students in academia and research working in synthetic organic, inorganic and bioorganic chemistry. | | Note de contenu : | In summary :
1. General Introduction.
2. Carbon Cumulenes.
3. Dicarbon Cumulenes.
4. Tricarbon Cumulenes.
5. Noncarbon Cumulenes. |
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